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A bond cleavage where shared pair of electrons is distributed equally to bonded atom after the cleav - Organic Chemistry I Flashcards



Nitro group -NO 2 ii.







This is accomplished through the reaction of ammonia and boron trifluoride.







The mixture of gaseous products containing oxygen is passed over red-hot coke when all the oxygen is converted to carbon monoxide.







The covalent bond can be represented by a dash joining mutually bonded atoms.







mp3? Formation of Covalent Bonds Nonmetal atoms frequently form covalent bonds with other nonmetal atoms.


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Description: Benzene ring can as well be considered as substituent when it is attached to an alkane with a functional group.

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    +396reps
    Heterolytic cleavage. In heterolytic cleavage, or heterolysis, the bond breaks in such a fashion that the originally- shared pair of electrons remain with one of the fragments. Thus, a fragment gains an electron, having both bonding electrons, while the other fragment loses an electron. [4] This process is also known as ionic fission.
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    +382reps
    Bonding electrons shared unequally between two atoms. Partial charges on atoms. (unequally shared)-electrons spend more time near the larger nucleus larger negative charge and small positive charge-electron cloud is bigger on atom with greater electronegativity-partial negative form with greater electronegativity
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    +33reps
    A covalent bond between atoms that differ in electronegativity. The shared electrons are pulled closer to the more electronegative atom, making it slightly negative and the other atom slightly positive.
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    +345reps
    The dash representing a bond. H has no electrons unbonded, O has 4 electrons unbonded, F has 4 electrons unbonded, and O has 6 electrons unbonded where the bond is a lone pair donated from F. Formal Charge: Number Valence electrons - Number of bonds - number of unbonded electrons H = 1 - 1 - 0 = 0 First Oxygen = 6 - 2 - 4 = 0 F = 7 - 2 - 4 = +1
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    Homolytic vs Heterolytic Bond Cleavage. Bond cleavage, or scission, is the splitting of chemical bonds. This can be generally referred to as dissociation when a molecule is cleaved into two or more fragments. In general, there are two classifications for bond cleavage: homolytic and heterolytic, depending on the nature of the process (Figure 7.2).
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